thermodynamic equilibrium constant

According to thermodynamic principle, this thesis reconsiders the equilibrium constant of ideal gas reaction.

本文依据热力学原理, 重新审议了理想气体的化学平衡常数.

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Results computed from Scatchard-Hildebrand model, Guggenheim quasi-lattice model, Wilson model and NRTL model are fairly approximate to those obtained from experimental data treatment and the values of thermodynamic equilibrium constant determined from these four models coincide with each other.

由Scatchard－Hildebrand模型、Guggenheim似晶格模型、Wilson模型和NRTL模型计算得出的活度系数值与实验值符合较好，从这四种模型测得的革取平衡常数值也互相符合一致。

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On Thermodynamic Equilibrium Constant

关于热力学平衡常数

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In this paper, ion exchange equilibrium isotherms for natural mordenite ( Jinyun Xian, Zhejiang province) and synthetic mordenite in ammonium-potassium and ammonium-silver systems along with the calculated thermodynamic equilibrium constant and Gibb's free energy change ⊿ G ° are presented.

测定了NH4~+-K~+、NH4~+-Ag~+两个体系在浙江省缙云县岱石口的天然丝光沸石和合成丝光沸石上的离子交换平衡等温线，并计算出其热力学平衡常数Ka和标准自由能变化△G~0。

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Detailed thermodynamic based analysis was presented for the chemical reactions in a hydrogasifier through the analysis of Gibbs free energy, chemical equilibrium constant and the equilibrium conversion rate.

通过研究吉布斯自由能、化学平衡常数及平衡转化率的变化，对加氢气化炉内主、次化学反应进行了系统的热力学分析。

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A thermodynamic study was conducted on the main and side reactions of synthesizing 4-methyl-pentene-1 through dimerization of propane. The influence of reaction temperature and pressure on chemical equilibrium constant were worked out.

采用热力学方法研究了丙烯二聚合成4甲基戊烯1过程中的主、副反应，计算了反应温度、反应压力对化学平衡常数的影响。

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The Investigation of the Effect of the Size on the Thermodynamic Properties and the Equilibrium Constant of Nanoparticles

粒度对纳米粒子热分解热力学性质和平衡常数的影响

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The thermodynamic criterion and the equilibrium constant criterion of the gold leaching with iodide were proposed. The leaching system of gold with iodine-iodide was thermodynamically analyzed.

通过推导碘化物浸金过程的热力学判据，提出碘化物浸金的平衡常数判据，对碘-碘化物浸金体系进行了热力学分析。

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Both approaches need thermodynamic data; the difference only lies in that equilibrium constants are needed as data base in the equilibrium constant approach whereas Gibbs free energy values are needed in the Gibbs free energy approach.

两种方法都需要热力学数据，所不同的是平衡常数法需要的是反应平衡常数，而自由能法需要物种自由能数据。

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