1、

Single Electron Transfer ( SET) reaction is a rising front field.

有机化合物的单电子转移反应(SET)是一个新兴的前沿领域。

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A new tetraphenyl porphyrin anthraquinone bridged by peptide bond, as a compound for studying photo induced electron transfer, was synthesized recently. The photo induced intramolecular electron transfer reactions of this compound were studied by Time Correlated Single Photon Counting method in different solvents.

首次合成了肽键桥连的四苯卟啉-蒽醌(TPP-AQ)化合物,以此作为研究光合成电子传递的模型化合物,用时间相关单光子荧光技术研究了该化合物在不同溶剂中分子内的电子转移。

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Rigid conjugated main chain is an important feature of conjugated polymers, it can formed large conjugated π electron system, so that the charge can transfer within the molecule. Thus, a single quencher molecule can cause a super-quenching of the entire polymer chain.

含有刚性共轭主链是共轭聚合物的重要特征,能在分子内形成大的共轭π电子体系,从而使电荷在分子内进行传输,单个猝灭剂分子就足以引起聚合物荧光的超猝灭。

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