Alkylation of Toluene with tert-Butyl Alcohol over H Type Mordenite Catalyst

The study was made of gas N alkylation of aniline and alcohol in fixed bed reactor.

用固定床反应器对苯胺和醇类气相N烷基化反应进行了研究。

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We explored the mechanism of the C alkylation between 5-chloromethyl-8-hydroxyquinoline and aromatic amines.

3对5-氯甲基-8-羟基喹啉与芳胺C烷基化反应的机理进行研究。

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Seven new β-DDB derivatives were prepared from gallic acid in 9 steps such as Ullmann coupling reaction, alkylation, benzoylation etc. The structures of these compounds were identified by(()~ 1HNMR.)

以没食子酸为原料，通过Ullmann偶合反应、烷基化、酰基化等9步反应合成了7种-βDDB的衍生物，其结构经1HNMR确认。

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This chapter was using different synthetic strategies to obtain target ligand: A is by Friedel Crafts acylation reaction followed by Mcmurry reaction; B is by classical Suzuki coupling reaction.

本章分别采用不同的合成策略得到目标配体：A是经付克酰基化与迈克摩尔反应；B是选用Suzuki偶合反应。

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Firstly the intermediate 2-( 2-hydroxyphenyl) phenylphosphinic acid ( HPPA) was prepared in 92.5% yield through continuous esterification, acylation and hydrolysis.

首先将酯化、酰基化、水解反应连续进行，得到了中间体2-（2-羟基苯基）苯基膦酸（HPPA），收率92.5%。

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As an intermediate for COX-2 inhibiters, 4-( methylthio) benzeneacetic acid(ⅳ) was prepared via Friedel-Crafts and Willgerodt-Kindler reaction from thioanisole(ⅰ).

以茴香硫醚（Ⅰ）为原料，经Friedel-Crafts酰基化、Willgerodt-Kindler反应合成了COX-2抑制剂的中间体4-甲硫基苯乙酸（Ⅳ）。

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The esterification of terpineol, the hydration and polymerization of α-pinene, the dimerization of rosin and the Friedel-Crafts acylation are important processes in the fine chemical industry. These reactions are concerned with larger molecule reactants using strong acid as catalysts.

松油醇酯化、松节油水合与聚合、松香二聚以及傅.克酰基化反应在工业上有着广泛的应用，它们都是重要的酸催化反应。

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During the acetylation of ( 3-bromopropyl) benzene the products of the halogen exchange are observed, a reasonable explanation for the phenomenon is proposed and the disposal of the acetylation of ( 3-bromopropyl) benzene is studied at the same time.

对3-溴丙基苯的付克酰基化反应进行了研究，发现了卤素交换的现象，并对此做了合理的解释，同时对该反应的后处理进行了研究。

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Racemic 2-methyl-1-phenylpropylamine was obtained by Friedel-Crafts reaction of benzene and isobutyryl chloride with the yield of 75.0%, then followed by Leuckart reaction in 85.0% yield.

本文以苯、异丁酰氯为原料通过傅克酰基化反应得到2-甲基-1-苯基丙酮，收率75.0%。

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Toluene was reacted with isobutyryl chloride in the presence of aluminum chloride to give 2 methyl 1 ( 4 methylphenyl) propanone in 75% yield.

收率为92%～93%.在催化剂无水三氯化铝存在下，甲苯与异丁酰氯进行酰基化反应得2甲基1（4甲基苯基）丙酮，收率为75%。

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The Friedel-Crafts acylation reactions of benzothiophene were carried out, and the effect of microwave radiation on the reaction was analyzed.

对苯并噻吩的傅-克酰基化反应进行了研究，并讨论了微波辐射对反应的影响。

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The paper discussed two acidylating reaction of Norfloxacinum, and the feasibility of appling these two reactions to teaching experiments.

本文探讨了氟哌酸的两个酰基化反应，及其作为教学实验的可行性。

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Effect of nitrobenzene on preparation of carboxyl polystyrene by Friedel-Crafts acylation reaction

硝基苯对傅克酰基化反应制备羧基化聚苯乙烯的影响

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In this paper, the catalytic properties of four kinds of zeolite molecular sieves were studied in acylation reaction to synthesize anthraquinone by benzene and phthalic anhydride, the appropriate HM-3 zeolite molecular sieves was selected, on which the modification was studied.

本文研究了四种H-型沸石分子筛在苯与苯酐合成蒽醌的酰基化反应中的催化性能，优选出较适宜的沸石分子筛HM-3，并在此基础上进行改性研究。

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The synthetic routes of CV-4151 were studied and the total yield of 9 steps amounted to 16. 2%. The structure was elucidated through physic-chemical properties and spectroscopic analyses.

主要通过傅克酰基化反应、氧化反应、魏悌希反应等九步反应合成了CV-4151，总收率达16.2%，其化学结构经核磁共振氢谱、红外光谱确证。

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Low substituted dibenzo [ fg, op] naphthacenes were synthesized by using Friedel-Crafts acylation, tadem aldol-Michael solvent-free reaction and palladium catalyzed dehydrohalogenation cyclization as key steps.

以傅克酰基化反应、串联的Aldol-Michael反应及Pd-催化的脱卤化氢环化反应为关键步骤，合成了低取代的二苯并并四苯衍生物（DBN）。

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The key intermediate, Ethyl 4-( 4-ethoxy-4-oxobutyl) benzoate ( 6), was obtained from benzene via Friedel-Crafts acylation, Huang reduction, saponification followed by acidification and esterification in 36.6% yield.

以苯作为起始原料，经过Friedel-Crafts酰基化反应、黄鸣龙还原、皂化和酯化等合成了其关键中间体4-（4-乙氧基-4-氧正丁基）苯甲酸乙酯（6），收率为36.6%。

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Up to now, the methods for preparing aromatic ketones still involve homogeneous metal chlorides or protonic acid used as catalysts in batch reactors via Friedel-Crafts acylation in industry.

目前，工业上通过Friedel-Crafts酰基化反应制备芳酮类化合物的工艺仍然是以均相的金属氯化物或质子酸等为催化剂，采用釜式反应器。

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Friedel-Crafts acylation is one of the most important synthetic reactions for the preparation of aromatic ketones, which are widely used as intermediates in fine chemicals and pharmaceutical industries.

芳酮类化合物是重要的精细化工和医药中间体，Friedel-Crafts酰基化反应是合成芳酮类化合物的最重要的方法。

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Method ( 2H)-2-cyclohexyl-3,4-dihydropyrrolo [ 1,2-a] pyrazin-1-one was synthesized from methyl pyrrole-2-carboxylate via substitution and cyclization, and the target compounds 6-aryl derivatives were obtained by Friedel-Crafts reaction.

方法以2-吡咯甲酸甲酯为原料，经取代、环合，制备（2H）-2-环己基-3,4-二氢吡咯[1,2-a]吡嗪-1-酮（3）；通过Friedel-Crafts酰基化反应，制得其6-酰基衍生物4a~4j。

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